Volume 39, Issue 8 pp. 1470-1472
Communication

Low-Temperature, Catalyzed Growth of Indium Nitride Fibers from Azido-Indium Precursors

Sean D. Dingman

Sean D. Dingman

Department of Chemistry Washington University St. Louis, MO 63130-4899 (USA) Fax: (+1) 314-935-4481

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Nigam P. Rath Dr.

Nigam P. Rath Dr.

Department of Chemistry and Center for Molecular Electronics University of Missouri – St. Louis St. Louis, MO 63121 (USA)

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Paul D. Markowitz

Paul D. Markowitz

Department of Chemistry Washington University St. Louis, MO 63130-4899 (USA) Fax: (+1) 314-935-4481

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Patrick C. Gibbons Prof.

Patrick C. Gibbons Prof.

Department of Physics Washington University St. Louis, MO 63130-4899 (USA)

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William E. Buhro Prof.

William E. Buhro Prof.

Department of Chemistry Washington University St. Louis, MO 63130-4899 (USA) Fax: (+1) 314-935-4481

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This work was supported by the U.S. National Science Foundation (Grant CHE-9709104). We gratefully acknowledge assistance from Dr. W. R. Winchester with GC-MS and Dr. Couture with X-ray fluorescence studies.

Graphical Abstract

New blue/violet laser diodes and LEDs need InN-containing alloys to provide the light-emitting constituents, but InN typically requires crystal growth temperatures (427 – 550 °C) commensurate with its decomposition. A new method allows InN synthesis as a fiber (see picture) at only 203 °C. This method suggests new approaches to produce thermally unstable materials.

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