Angewandte Chemie International Edition
Volume 38, Issue 23 pp. 3488-3492
Communication

Interpenetrated and Noninterpenetrated Three-Dimensional Networks in the Polymeric Species Ag(tta) and 2 Ag(tta)⋅AgNO3 (tta=tetrazolate): The First Examples of the μ4-η1:η1:η1:η1 Bonding Mode for Tetrazolate

Lucia Carlucci, 

Lucia Carlucci

Dipartimento di Biologia Strutturale e Funzionale, Universitá dell'Insubria, Via J. H. Dunant 3, I-21100 Varese, Italy

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Gianfranco Ciani, 

Gianfranco Ciani

Dipartimento di Chimica Strutturale, e Stereochimica Inorganica and Centro CNR, Via G. Venezian 21, I-20133 Milano, Italy, Fax: (+390) 2-70-63-52-88

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Davide M. Proserpio, 

Davide M. Proserpio

Dipartimento di Chimica Strutturale, e Stereochimica Inorganica and Centro CNR, Via G. Venezian 21, I-20133 Milano, Italy, Fax: (+390) 2-70-63-52-88

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First published: 30 November 1999
https://doi.org/10.1002/(SICI)1521-3773(19991203)38:23<3488::AID-ANIE3488>3.0.CO;2-H
Citations: 90

Abstract

A twofold interpenetrated neutral three-dimensional network with rectangular channels (left) and a noninterpenetrated three-dimensional cationic framework (right) are the stuctural motifs observed in the simple salt Ag(tta) and in the double salt 2 Ag(tta)⋅AgNO3, respectively. These compounds exhibit the first examples of the μ4-η1:η1:η1:η1 bonding mode for tetrazolate (tta).

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