Volume 38, Issue 1-2 pp. 108-110
Communication

Isonitroso Hydrogen (Hydroxy Nitrene, HON)

Günther Maier

Günther Maier

Institut für Organische Chemie der Universität, Heinrich-Buff-Ring 58, D-35392 Giessen (Germany), Fax: (+49) 641-99-34309

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Hans Peter Reisenauer

Hans Peter Reisenauer

Institut für Organische Chemie der Universität, Heinrich-Buff-Ring 58, D-35392 Giessen (Germany), Fax: (+49) 641-99-34309

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Michael De Marco

Michael De Marco

Institut für Organische Chemie der Universität, Heinrich-Buff-Ring 58, D-35392 Giessen (Germany), Fax: (+49) 641-99-34309

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Abstract

Such a simple compound, and yet only now has HON (2) been prepared for the first time in a matrix at 10 K in a manner analogous to that applied many years ago for HNO (1), which is important for combustion processes, atmospheric chemistry, astrophysics, and particularly theoretical chemistry. A photoequilibrium exists in the matrix between 2 and 1.

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