Journal of Polymer Science Part A: Polymer Chemistry

Article

Preparation of functionally gradient fluorocarbon polymer films by plasma polymerization of NF₃ and propylene

Akimasa Tasaka

Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Tanabe-cho, Tsuzuki-gun, Kyoto 610-03, Japan

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Akiko Komura,

Akiko Komura

Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Tanabe-cho, Tsuzuki-gun, Kyoto 610-03, Japan

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Yoshiharu Uchimoto,

Yoshiharu Uchimoto

Division of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, Japan

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Minoru Inaba,

Corresponding Author

Minoru Inaba

Division of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, Japan

Division of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, JapanSearch for more papers by this author

Zempachi Ogumi,

Zempachi Ogumi

Division of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, Japan

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Akimasa Tasaka,

Akimasa Tasaka

Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Tanabe-cho, Tsuzuki-gun, Kyoto 610-03, Japan

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Akiko Komura,

Akiko Komura

Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Tanabe-cho, Tsuzuki-gun, Kyoto 610-03, Japan

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Yoshiharu Uchimoto,

Yoshiharu Uchimoto

Division of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, Japan

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Minoru Inaba,

Corresponding Author

Minoru Inaba

Division of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, Japan

Division of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, JapanSearch for more papers by this author

Zempachi Ogumi,

Zempachi Ogumi

Division of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, Japan

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First published: 30 January 1996

https://doi.org/10.1002/(SICI)1099-0518(19960130)34:2<193::AID-POLA5>3.0.CO;2-V

Citations: 8

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Abstract

Fluorocarbon polymer films were prepared by plasma polymerization using nitrogen trifluoride (NF₃) and propylene as starting materials. To improve their adhesiveness to substrates, a novel functionally gradient film in which the content of fluorine decreased continuously from the surface to the interior was prepared by changing source gas composition during deposition. This film had a smooth and pinhole-free surface, and had a high contact angle (110°) for water drop. In addition, it showed good adhesion to a glass substrate. © 1996 John Wiley & Sons, Inc.

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Volume34, Issue2

30 January 1996

Pages 193-198

Preparation of functionally gradient fluorocarbon polymer films by plasma polymerization of NF₃ and propylene

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Preparation of functionally gradient fluorocarbon polymer films by plasma polymerization of NF₃ and propylene